Bocarsly Lab

Princeton Electrochemistry

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2025

Alma Paola Hernandez-Gonzalez, Stephanie Dulovic, Guangming Cheng, Cynthia Bian, Alyssa Ritchie, and Andrew Bocarsly

Electroanalytical Implications of an Interfacial Insulating Metal Oxide Layer: Impact of a Porous Cr2O3-Ga2O3 Layer on Electron Transfer and Heterogeneous Electrocatalysis.  ACS Electrochemistry,2025 1(10), 2223–2235. Article

2024

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Josef Lawrence, Stephanie Dulovic, Kai Filsinger, Scott Lee, and Andrew B. Bocarsly

Extending Cyanogel and Prussian Blue Analogue Chemistry to Octacyanometallate-Based Coordination Polymers: Reduced Temperature Routes to Materials Based on Molybdenum and Tungsten.  Chem. Mater., 2024, 36(16), 7857–7866 Article

Kailyn Y. Cohen, Hovnan Simonyan, Mason Ortiz, Benjamin F. Solomon, Luke Simkins, Raymond N. Dominey, Emma W. Goldman, and Andrew B. Bocarsly

Exploration of Pynaphthyridine and Binaphthyridine Manganese(I) Tricarbonyl Complexes: Influence on Carbon Dioxide Reduction Electrocatalysis  Organometallics, 2024, 43(14), 1517–1527 Article

2023

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Kailyn Y. Cohen, Rebecca Evans, and Andrew B. Bocarsly

Extending the π-system in Mn(I) Diimine Tricarbonyl Complexes:Impacts on Photochemistry, Electrochemistry, and CO2 Catalytic Reduction Activity Eur. J. Inorg. Chem. 2023, e202300435 Article

Kailyn Y. Cohen, Delaan G. Nedd, Rebecca Evans, and Andrew B. Bocarsly

Mechanistic insights into CO2 conversion to CO using cyano manganese complexes. Dalton Trans. 2023, 52, 7524-7537. Article

Cronin, Steve; Dulovic, Stephanie; Lawrence, Josef; Filsinger, Kai; Hernandez-Gonzalez, Alma Paola; Evans, Rebecca; Stiles, Joseph; Morris, Jalah; Pelczer, István; Bocarsly, Andrew

Direct Synthesis of 1-Butanol with High Faradaic Efficiency from CO2 Utilizing Cascade Catalysis at a Ni-Enhanced (Cr2O3)3Ga2O3 Electrocatalyst. J. Am. Chem. Soc. 2023, 145, 12, 6762–6772 Article

2022

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Kailyn Y. Cohen, Adam Reinhold, Rebecca Evans, Tia S. Lee, Hsin-Ya Kuo, Delaan G. Nedd, Gregory D. Scholes, and Andrew B. Bocarsly

Elucidating the mechanism of photochemical CO2 reduction to CO using a cyanide-bridged di-manganese complex
Dalton Trans., 2022,51, 17203-17215 Article

Kailyn Y. Cohen, Rebecca Evans, Stephanie Dulovic, and Andrew B. Bocarsly

Using Light and Electrons to Bend Carbon Dioxide: Developing and Understanding Catalysts for CO2 Conversion to Fuels and Feedstocks Acc. Chem. Res. 2022, 55, 7, 944–954 Article

2020

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Hsin-Ya Kuo, Steven E Tignor, Tia S Lee, Danrui Ni, James Eujin Park, Gregory D Scholes, Andrew B Bocarsly

Reduction-induced CO dissociation by a [Mn(bpy)(CO) 4][SbF 6] complex and its relevance in electrocatalytic CO 2 reduction Dalton Trans. 2020 Jan 21;49(3):891-900 Article

Jessica J. Frick*, Guangming Cheng, Satya Kushwaha, Nan Yao, Sigurd Wagner*, Andrew B. Bocarsly, and Robert J. Cava

Observation of [VCu1–Ini2+VCu1–] Defect Triplets in Cu-Deficient CuInS2. J. Phys. Chem. C 2020, 124, 48, 26415–26427. Article

Brian M. Foster, Aubrey R. Paris, Jessica J. Frick, Daniel A. Blasini-Pérez, Robert J. Cava, and Andrew B. Bocarsly

Catalytic Mismatching of CuInSe2 and Ni3Al Demonstrates Selective Photoelectrochemical CO2 Reduction to Methanol ACS Appl. Energy Mater. 2020, 3, 1, 109–113 Article

2019

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Paris, A. R.; Bocarsly, A. B.

High-Efficiency Conversion of CO2 to Oxalate in Water Is Possible Using a Cr-Ga Oxide Electrocatalyst. ACS Catal. 2019, 9, 2324-2333. Article

Paris, A. R.*; Bocarsly, A. B.

Mechanistic Insights into C2 and C3 Product Generation Using Ni3Al and Ni3Ga Electrocatalysts for CO2 Reduction. Faraday Discuss. 2019, 215, 192-204. (*corresponding author) Article

Kuo, H.-Y.; Lee, T. S.; Chu, A. T.; Tignor, S. E.; Scholes, G. D.; Bocarsly, A. B.

A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO2 to CO. Dalton Trans. 2019, 1226-1236. Article

Tignor, S. E.; Kuo, H.-Y.; Lee, T. S.; Scholes, G. D.; Bocarsly, A. B.

Manganese-Based Catalysts with Varying Ligand Substituents for the Electrochemical Reduction of CO2 to CO. Organometallics 2019, 38, 1292-1299. Article

2018

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Frick, J. J.; Topp, A.; Klemenz, S.; Krivenkov, M.; Varykhalov, A.; Ast, C. R.; Bocarsly, A. B.; Schoop, L. M.

Single-Crystal Growth and Characterization of the Chalcopyrite Semiconductor CuInTe2 for Photoelectrochemical Solar Fuel Production. J. Phys. Chem. Lett. 2018, 9, 6833-6840. Article

Ni, D.; Kuo, H.-Y.; Park, J. E.; Lee, T. S.; Sloman, S.-R. I.; Cava, R. J.; Bocarsly, A. B.

Improved H2 Evolution in Quaternary SCIGS Chalcopyrite Semiconductors. J. Phys. Chem. C 2018, 122, 24512-24519. Article

Frick, J. J.; Cava, R. J.; Bocarsly, A. B.

Chalcopyrite CuIn(S1–xSex)2 for Photoelectrocatalytic H2 Evolution: Unraveling the Energetics and Complex Kinetics of Photogenerated Charge Transfer in the Semiconductor Bulk. Chem. Mater. 2018, 30, 4422-4431. Article

Paris, A. R.; Chu, A. T.; O’Brien, C. B.; Frick, J. J.; Francis, S. A.; Bocarsly, A. B.

Tuning the Products of CO2 Electroreduction on a Ni3Ga Catalyst Using Carbon Solid Supports. J. Electrochem. Soc. 2018, 165, H385-H392. Article

Park, J. E.; Hu, Y.; Krizan, J. W.; Gibson, Q. D.; Tayvah, U. T.; Selloni, A.; Cava, R. J.; Bocarsly, A. B.

Stable Hydrogen Evolution from an AgRhO2 Photocathode under Visible Light. Chem. Mater. 2018, 30, 2574-2582. Article

2017

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Ji, H.; Sahasrabudhe, G.; Vallon, M. K.; Schwartz, J.; Bocarsly, A. B.; Cava, R. J.

Investigating the origin of Co(IV)’s high electrocatalytic activity in the oxygen evolution reaction at a NaxCoO2 interface. Mater. Res. Bull. 2017, 95, 285-291. Article

Paris, A. R.; Bocarsly A. B.

Ni–Al Films on Glassy Carbon Generate an Array of Oxygenated Organics from CO2. ACS Catal. 2017, 7, 6815-6820. Article

Frick, J. J.; Kushwaha, S. K.; Cava, R. J.; Bocarsly, A. B.

Characterization of Primary Transport Properties of the Light-Harvesting Chalcopyrite Semiconductors CuIn(S1-xSex)2. J. Phys. Chem. C 2017, 121, 17046-17052. Article

Stufano, P.; Paris, A. R.; Bocarsly A.

Photoelectrochemical NADH regeneration using Pt-modified p-GaAs semiconductor electrodes. ChemElectroChem 2017, 4, 1066-1073. Article

Wuttig, A.; Krizan, J. W.; Gu, J.; Frick, J. J.; Cava, R. J.; Bocarsly A. B.

The effect of Mg-doping and Cu nonstoichiometry on the photoelectrochemical response of CuFeO2. J. Mater. Chem. A 2017, 5, (11), 165-171. Article

2016

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Pander III, J. E.; Fogg, A.; Bocarsly A. B.

Utilization of Electropolymerized Films of Cobalt Porphyrin for the Reduction of Carbon Dioxide in Aqueous Media. ChemCatChem 2016, 8, 3536-3545. Article

Pander III, J. E.; Baruch, M. F.; Bocarsly A. B.

Probing the Mechanism of Aqueous CO2 Reduction on Post-Transition-Metal Electrodes using ATR-IR Spectroelectrochemistry. ACS Catal. 2016, 6, (11), 7824-7833. Article

White, J. L.; Bocarsly A. B.

Enhanced Carbon Dioxide Reduction Activity on Indium-Based Nanoparticles. J. Electrochem. Soc. 2016, 163, 6, H410-H416. Article

Detweiler, Z. M.; Wulfsberg, S. M.; Frith, M. G.; Bocarsly, A. B.; Bernasek, S. L.

The Oxidation and Surface Speciation of Indium and Indium Oxides Exposed to Atmospheric Oxidants. Surface Science. 2016, 648, 188-195. Article

2015

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Zeitler, E. L.; Ertem, M. Z.; Pander III, J. E.; Yan, Y.; Batista, V. S.; Bocarsly, A. B.

Isotopic Probe Illuminates the Role of the Electrode Surface in Proton Coupled Hydride Transfer Electrochemical Reduction of Pyridinium on Pt(111). J. Electrochem. Soc. 2015, 162 (14), H938-H944. Article

White, J. L.; Baruch, M. F.; Pander III, J. E.; Hu, Y.; Fortmeyer, I. C.; Park, J. E.; Zhang, T.; Liao, K.; Gu, J.; Yan, Y.; Shaw, T. W.; Abelev, E.; Bocarsly, A. B.

Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes. Chem. Rev. 2015, 115 (23), 12888-12935. Article

Agarwal, J.*; Shaw, T. W.*; Schaefer III, H. F.; Bocarsly, A. B.

Design of a Catalytic Active Site for Electrochemical CO2 Reduction with Mn(I)-Tricarbonyl Species. Inorg. Chem. 2015, 54 (11), 5285-5294.

*co-first authors Article

Baruch, M. F.*; Pander III, J. E.*; White, J. L.; Bocarsly, A. B.

Mechanistic Insights into the Reduction of CO2 on Tin Electrodes using in Situ ATR-IR Spectroscopy. ACS Catal. 2015, 5, 3148-3156.
*co-first authors Article

Agarwal, J.; Stanton III, C. J. ; Shaw, T. W.; Vandezande, J. E.; Majetic, G. F.; Bocarsly, A. B.; Schaefer III, H. F.

Exploring the effect of axial ligand substitution (X = Br, NCS, CN) on the photodecomposition and electrochemical activity of [MnX(NC)(CO)3] complexes. Dalton Trans., 2015, 44, 2122-2131. Article

Liao, K.; Askerka, M.; Zeitler, E. L.; Bocarsly, A. B.; Batista, V. S.

Electrochemical Reduction of Aqueous Imidazolium on Pt(111) by Proton Coupled Electron Transfer. Top. Catal. 2015, 58 (1), 23-29. Article

Cole, E. B.; Baruch, M. F.; L’Esperance, R. P.; Kelly, M. T.; Lakkaraju, P. S.; Zeitler, E. L.; Bocarsly, A. B.

Substituent Effects in the Pyridinium Catalyzed Reduction of CO2 to Methanol: Further Mechanistic Insights. Top. Catal., 2015, 58 (1), 15-22. Article

2014

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Detweiler, Z. M.; White, J. L.; Bernasek, S. L.; Bocarsly, A. B.

Anodized Indium Metal Electrodes for Enhanced Carbon Dioxide Reduction in Aqueous Electrolyte. Langmuir 2014, 30 (25), 7593-7600. Article

White, J. L.; Herb, J. T.; Kaczur, J. J.; Majsztrik, P. W.; Bocarsly, A. B.

Photons to Formate: Efficient Electrochemical Solar Energy Conversion Via Reduction of Carbon Dioxide. J. CO2 Util. 2014, 7, 1-5. Article

Agarwal, J.; Shaw, T. W.; Stanton III, C. J.; Majetich, G. F.; Bocarsly, A. B.; Schaefer III, H. F.

NHC-Containing Manganese(I) Electrocatalysts for the Two-Electron Reduction of CO2. Angew. Chem. Int. Ed. 2014, 53 (20), 5152-5155. Article

Watkins, J. D.; Bocarsly, A. B.

Direct Reduction of Carbon Dioxide to Formate in High-Gas-Capacity Ionic Liquids at Post-Transition-Metal Electrodes. ChemSusChem 2014, 7, 284-290. Article

Gu, J.*; Yan, Y.*; Krizan, J. W.; Gibson, Q. D.; Detweiler, Z. M.; Cava, R. J.; Bocarsly, A. B.

p-Type CuRhO2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light. J. Am. Chem. Soc. 2014, 136 (3), 830-833.
*co-first authors Article

2013

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Appel, A. M.; Bercaw, J. E.; Bocarsly, A. B.; Dobbek, H.; DuBois, D. L.; Dupuis, M.; Ferry, J. G.; Fujita, E.; Hille, R.; Kenis, P. J. A.; Kerfeld, C. A.; Morris, R. H.; Peden, C. H. F.; Portis, A. R.

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation. Chem. Rev. 2013, 113, 6621-6658. Article

Yan, Y.; Gu, J.; Bocarsly, A. B.

Hydrogen Bonded Pyridine Dimer: A Possible Intermediate in the Electrocatalytic Reduction of Carbon Dioxide to Methanol. Aerosol and Air Quality Research 2014, 14 (2), 515-521. Article

Yan, Y.; Zeitler, E.L.; Gu, J.; Hu, Y.; Bocarsly, A.B.

Electrochemistry of Aqueous Pyridinium: Exploration of a Key Aspect of Electrocatalytic Reduction of CO2 to Methanol. J. Am. Chem. Soc. 2013, 135 (38), 14020-14023. Article

Gu, J.; Wuttig, A.; Krizan, J.W.; Hu, Y.; Detweiler, Z.D. Cava, R.J.; Bocarsly, A.B.

Mg-Doped CuFeO2 Photocathodes for Photoelectrochemical Reduction of Carbon Dioxide. J. Phys. Chem. C 2013, 117 (24), 12415-12422. Article

2012

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Bocarsly, A.B.; Gibson, Q.D.; Morris, A.J,; LEsperance, R.P.; Detweiler, Z.M.; Lakkaraju, P.S.; Zeitler, E.L.; Shaw, T.W.

Comparative Study of Imidazole and Pyridine Catalyzed Reduction of Carbon Dioxide at Illuminated Iron Pyrite Electrodes. ACS Catal. 2012, 2, 1684-1692. Article

2011

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Morris, A.J.; McGibbon, R.T.; Bocarsly, A.B.

Electrocatalytic Carbon Dioxide Activation: The Rate-Determining Step of Pyridinium-Catalyzed CO2 Reduction. ChemSusChem. 2011, 4 (2), 191-196. Article

2010

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Cole, E.B.; Lakkaraju, P.S.; Rampulla, D.M.; Morris, A.J.; Abelev, E.; Bocarsly, A.B.

Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights. J. Am. Chem. Soc. 2010, 132 (33), 11539-11551. Article

2009

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Burgess, C.M.; Yao, N; Bocarsly, A.B

Stabilizing cyanosols: amorphous cyanide bridged transition metal polymer nanoparticles. J. Mater. Chem. 2009, 19 (46), 8846-8855. Article

2008

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Bocarsly, A.B.; Niangar, E.

Electrocatalyst Design for an Elevated Temperature Proton Exchange Membrane Direct Ethanol Fuel Cell. ECS Trans. 2008, 16 (2), 1285-1291. Article

Majsztrik, P.W.; Bocarsly, A.B.; Benziger, J.B.

Viscoelastic Response of Nafion. Effects of Temperature and Hydration on Tensile Creep. Macromolecules. 2008, 41 (24), 9849-9862. Article

Majsztrik, P.W.; Bocarsly, A.B.; Benziger, J.B.

Water Permeation Through Nafion Membranes: The Role of Water Activity. J. Phys. Chem. B. 2008, 112 (51), 16280-16289. Article

2007

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Nicotera, I.; Zhang, T.; Khalfan, A.; Bocarsly, A.B.; Greenbaum, S.

NMR Characterization of Composite Polymer Membranes for Low Humidity PEM Fuel Cells. J. Electrochem. Soc. 2007, 154 (5), B466-B473. Article

Vondrova, M.; Burgess, C.; Bocarsly, A.B.

Cyanogel Coordination Polymers as Precursors to Transition Metal Alloys and Intermetallies – from Traditional Heating to Microwave Processing. Chem. Mater. 2007, 19 (9), 2203-2212. Article

Majsztrik, P.; Satterfield, B.M.; Bocarsly, A.B.; Benziger, J.B.

Water Sorption, Desorption and Transport in Nafion Membranes. J. Membr. Sci. 2007, 301 (1-2), 93-106. Article

Majsztrik, P.; Bocarsly, A.B.; Benziger, J.B.

An Instrument for Environmental Control of Vapor Pressure and Temperature for Tensile Creep and other Mechanical Property Measurements. Rev. Sci. Instrum. 2007, 78 (10), 103904-103904-7. Article

Persad, S.; Chow, K.F.; Wang, W.; Wang, E.; Okafor, A.; Jesperson, N.; Mann, J.; Bocarsly, A.B.

NMR Investigation of Dye-doped Sol-gels for Ammonia Gas Sensing. Sens. Actuators B: Chemical. 2008, 129(1), 359-363 Article

Barton, E.E.; Rampulla, D.M.; Bocarsly, A.B.

Selective Solar-driven Reduction of CO2 to Methanol Using a catalyzed p-GaP based photoelectrochemical cell. J. Am. Chem. Soc. 2008, 130 (20), 6342-6345. Article

Vondrova, M.; McQueen, T.M.; Burgess, C.M.; Ho, D.M.; Bocarsly, A.B.

The Autoreduction of Pd-Co and Pt-Co Cyanogels: Exploration of Cyanometalate Coordination Chemistry at Elevated Temperatures. J. Am. Chem. Soc. 2008, 130 (16), 5563-5572. Article

Nicotera, I.; Khalfan, A.; Goenaga, G.; Zhang, T.; Bocarsly, A.B.

NMR Investigation of Water and Methanol Mobility in Nano-composite Fuel Cell Membranes. Ionics. 2008, 14 (3), 243-253. Article

Burgess, C.M.; Vondrova, M.; Bocarsly, A.B.

A Versatile Chemical Method for the Formation of Macroporous Transition Metal Alloys from Cyanometalate Coordination Polymers. J. Mater. Chem. 2008, 18, 3694-3701. Article

2006

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Adjemian, K.T.; Dominey, R.; Krishnan, L.; Ota, H.; Majsztrik, P.W.; Zhang, T.; Mann, J.; Kirby, B.; Gatto, L.; Velo-Simpson, M.; Leahy, J.; Srinivasan, S.; Benziger, J.B.; Bocarsly, A.B.

Function and Characterization of Metal Oxide-Nafion Composite Membranes for Elevated Temperature H2/O2 PEM Fuel Cells. Chem. Mater. 2006, 18, 2238-2248. Article

Mann, J.; Yao, N.; Bocarsly, A.B.

Characterization and Analysis of New Catalysts for a Direct Ethanol Fuel Cell. Langmuir. 2006, 22, 10432-10436. Article

Satterfield, M.B.; Majsztrik, P.W.; Ota, H.; Benziger, J.B.; Bocarsly, A.B.

Mechanical Properties of Nafion and Titania/Nafion Composite Membranes for Polymer Electrolyte Membrane Fuel Cells. J. Polym. Sci. Part B: Polym. Phys. 2006, 44, 2327-2345. Article

2005

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Chen, S.L.; Bocarsly, A.B.; Benziger, J.B.

Nation-layered Sulfonated Polysulfone Fuel Cell Membranes. J. Power Sources. 2005, 152, 27-33. Article

Chen, S.L.; Benziger, J.B.; Bocarsly, A.B.; Zhang, T.

Photo-cross-linking of Sulfonated Styrene-ethylene-butylene Copolymer Membranes for Fuel Cells. Ind. Eng. Chem. Res. 2005, 44, 7701-7705. Article

Vondrova, M.; Klimczuk, T.; Miller, V.L.; Kirby, B.W.; Yao, N.; Cava, R.J.; Bocarsly, A.B.

Supported Superparamagnetic Pd/Co Alloy Nanoparticles Prepared from a Silica/Cyanogel Co-gel. Chem. Mater. 2005, 17, 6216-6218. Article

Vondrova, M.; Majsztrik, P.W.; Gould, S.; Bocarsly, A.B.

Solid-State Chemistry in a Microwave Oven: Preparation of Pd/Co Alloy from Cyanogel Coordination Polymers. Chem. Mater. 2005, 17 (19), 4755-4757. Article

Wang, E.; Chowa, K.F.; Wanga, W.; Wong, C.; Yee, C.; Persad, A.; Mann, J.; Bocarsly, A.B.

Optical Sensing of HCI with Phenol Red Doped Sol-Gels. Anal. Chim. Acta. 2005, 534, 301-306. Article

2004

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Chen, S.L.; Krishnan, L.; Srinivasan, S.; Benziger, J.B.; Bocarsly, A.B.

Ion Exchange Resin/poly Styrene Sulfonate Composite Membranes for PEM Fuel Cells. J. Membr. Sci. 2004, 243, 327-33. Article

Yang, C.; Srinivasan, S.; Bocarsly, A.B.; Tulyani, S.; Benziger, J.B.

A Comparison of Physical Properties and Fuel Cell Performance of Nafion and Zirconium Phosphate/Nafion Composite Membranes. J. Membr. Sci. 2004, 237, 145-161. Article

Watson, D.F.; Tan, H.S.; Schreiber, E.; Mordas, C.J.; Bocarsly, A.B.

Femtosecond Pump-Probe Spectroscopy of Trinuclear Transition Metal Mixed-Valence Complexes. J. Phys. Chem. A. 2004, 108, 3261-3267. Article

2003

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Srinivasan, S.; Kirshnan, L.; Bocarsly, A.B.; Hsueh, K.-L.; Lai, C.-C.; Peng, A.

Fuel Cells versus Competing Technologies. Proceedings of the First International Fuel Cell, Science, Engineering and Technology Conference, Rochester, New York, 2003, 225-232. Article

Wang, E.; Chow, K.-F.; Kwan, V.; Chin, T.; Wong, C.; Bocarsly, A.B.

Fast and Long Term Optical Sensors for pH Based on Sol-Gels. Anal. Chim. Acta. 2003, 495, 45-50. Article

Deshpande, R.S.; Sharp-Goldman, S.L.; Willson, J.L.; Bocarsly, A.B.; Gross, J.; Finnefrock, A.C.; Gruner, S.M.

The Morphology and Gas Adsorption Properties of the Palladium-Cobalt Based Cyanogels. Chem. Mater. 2003, 15, 4239-4246. Article

Haataja, M.; Srolovitz, D.J.; Bocarsly, A.B.

Morphological Stability during Electrodeposition II: Additive Effects. J. Electrochem. Soc. 2003, 150 (10), C708-C716. Article

Haataja, M.; Srolovitz, D.J.; Bocarsly, A.B.

Morphological Stability during Electrodeposition I: Steady States and Stability Analysis. J. Electrochem. Soc. 2003, 150 (10), C699-C707. Article

2002

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Aparicio, M.; Klein, L.C.; Adjemian, K.T.; Bocarsly, A.B.

SiO2-P2O5-ZrO2 sol-gel/Nafion® Composite Membranes for PEMFC. Ceram. Trans. 2002, 127, 167. Article

Costamagna, P.; Yang, C.; Bocarsly, A.B.; Srinivasan, S.

Nafion® 115/Zirconium Phosphate Composite Membranes for Operation of PEMFCs above 100°C. Electrochim. Acta. 2002, 47, 1023-1033. Article

Pfenning, B.W.; Mordas, C.J.; McCloskey, A.; Lockard, J.V.; Salmon, P.M.; Cohen, J.L.; Watson, D.F.; Bocarsly, A.B.

Excited-State Electronic Coupling and Photoinduced Multiple Electron Transfer in Two Related Ligand-Bridged Hexanuclear Mixed-Valence Compounds. Inorg. Chem. 2002, 41, 4389. Article

Tulyani, S.; Adjemian, K.T.; Krishnan, L.; Yang, C.; Srinivasan, S.; Bocarsly, A.B.; Benziger, J.B.

Developing High-Temperature CO Tolerant Polymer Electrolyte Membrane Fuel Cells. Proceedings of the ACS Conference, Boston, Massachusetts, 2002, 47 (2), 675-676. Article

Deshpande, R.S.; Sharp-Goldman, S.L.; Bocarsly, A.B.

Thermodynamics and Kinetics of CO2 Adsorption on Dehydrated Palladium Cobalt Based Cyanogels: A Highly Selective, Fully Reversible System for CO2 Storage. Langmuir. 2002, 18 (20), 7694-7698. Article

Dokoutchaev, A.G.; Abdelrazzaq, F.; Thompson, M.E.; Willson, J.; Chang, C.; Bocarsly, A.B.

Multicomponent Electrodes for Water Oxidation: From Combinatorial to Individual Electrode Study. Chem. Mater. 2002, 14, 3343-3348. Article

Adjemian, K.T.; Srinivasan, S.; Benziger, J.B.; Bocarsly, A.B.

Investigation of PEMFC Operation above 100°C Employing Perfluorosulfonic Acid Silicon Oxide Composite Membranes. J. Power Sources. 2002, 109, 356-364. Article

Watson, D.F.; Willson, J.L.; Bocarsly, A.B.

Photochemical Image Generation in a Cyanogel System Synthesized from Tetrachloropalladate(II) and the Trimetallic Mixed-Valence Complex, [(NC)5FeII-CN-PtIV(NH3)4-NC-FeII(CN)5]4-: Consideration of Photochemical and Dark Mechanistic Pathways of Prussian Blue Formation. Inorg. Chem. 2002, 41, 2408-2416. Article

Yang, C.; Costamagna, P.; Srinivasan, S.; Benziger, J.B.; Bocarsly, A.B.

Approaches and Technical Challenges to High Temperature Operation of Proton Exchange Membrane Fuel Cells. J. Power Sources. 2001, 103, 1-9. Article

Watson, D.F.; Bocarsly, A.B.

The Effects of Electronic Coupling and Solvent Broadening on the Intervalent Electron Transfer of a Centrosymmetric Mixed-Valence Complex. Coord. Chem. Rev., 2001, 211, 177-194. Article

Adjemian, K.T.; Lee, S.J.; Srinivasan, S.; Benziger, J.B.; Bocarsly, A.B.

Silicon Oxide/Nafion® Composite Membranes for PEMFC Operation at 80-140°C. J. Electrochem. Soc., 2002, 149 (3), A256-A261. Article

2000

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Bocarsly, A.B.; Willson, J.; Sharp, S.

Cyanogels: Coordination Polymer Hydrogels having Applications in Materials Chemistry. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2000, 41 (1), 722-723. Article

Kelly, M.T.; Arbuckle-Keil, G.A.; Johnson, L.A.; Su, E.Y.; Amos, L.J.; Chun, J.K.M.; Bocarsly, A.B.

Nickel Ferrocyanide Modified Electrodes as Active Cation Exchange Matrices: Real Time XRD Evaluation of Overlayer Structure and Electrochemical Behavior. J. Electroanal. Chem. 2001, 500, 311-321. Article

Watson, D.F.; Bocarsly, A.B.

Interfacial Photoannealing: The Light Driven Alteration of the Surface-Binding Geometry of a Trimetallic Mixed-Valence Complex on Colloidal TiO2. J. Phys. Chem. B. 2000, 104 (46), 10940-10948. Article

Hennessy, M.H.; Soos, Z.G.; Watson, D.F.; Bocarsly, A.B.

Raman Excitation Profiles with Self-Consistent Excited-State Displacements. J. Phys. Chem. B. 2000, 104 (46), 10909-10914. Article

Meagher, K.K.; Bocarsly, A.B.; Bernasek, S.L.; Tamanarayanan, T.A.

Interaction of Neopentyl Thiol with Clean and Oxygen-Modified Fe(100) Surfaces. J. Phys. Chem. B. 2000, 104 (14), 3320-3326. Article

Schwartz, J.; Gawalt, E.S.; Lu, G.; Milliron, D.J.; Purvis, K.L.; Woodson, S.J.; Bernasek, S.L.; Bocarsly, A.B.; VanderKam, S.K.

Organometallic Chemistry at the Interface with Materials Science. Polyhedron. 2000, 19, 505-507. Article

Chang, C.C.; Pfennig, B.; Bocarsly, A.B.

Photoinduced Multielectron Charge Transfer Processes in Group 8-Platinum Cyanobridged Supramolecular Complexes. Coord. Chem. Rev. 2000, 208, 33-45. Article

1999

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Bernasek, S.L.; Schwartz, J.; Bocarsly, A.B.; Lu, G.; Purvis, K.; VanderKam, S.

Synthesis and Ligand Metathetical Reactions of Surface-Bound Organometallic Interfaces. Spec. Publ. – R. Soc. Chem. 1999, 235, 341. Article

Smelyanskiy, V.N.; Dykman, M.I.; Rabitz, H.; Vugmeister, B.E.; Bernasek, S.L.; Bocarsly, A.B.

Nucleation in Periodically Driven Electrochemical Systems. J. Chem. Phys. 1999, 110, 11488-11504. Article

Chang, C.C.; Bocarsly, A.B.

Oxidation of Halides by Redox Enhanced Ferricyanide in the [FeII-CN-PtIV]n Coordination Polymer: An Optically Triggered Process. J. Electroanal. Chem. 1999, 470, 99-113. Article

VanderKam, S.K.; Gawalt, E.S.; Schwartz, J.; Bocarsly, A.B.

Electrochemically Active Surface Zirconium Complexes on Indium Tin Oxide. Langmuir. 1999, 15 (19), 6598-6600. Article

Pfennig, B.W.; Lockard, J.V.; Cohen, J.L. (Vassar College); Watson, D.F.; Ho, D.M.; Bocarsly, A.B. (Princeton University)

Synthesis, Characterization, and Photochemistry of a Dinuclear Cyanide-Bridged Iron(II)-Platinum(IV) Mixed-Valence Compound and its Implications for the Corresponding Iron(II)-Platinum(IV)-Iron(II) Complex. Inorg. Chem. 1999, 38 (12), 2941-2946. Article

1998

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Chang, C.C.; Ludwig, D.; Bocarsly, A.B.

Redox Reactivity as the Controlling Element in Coordination Polymer Stereochemistry: Redox Switched Growth Mechanism in the [FeII-CN-PtIV]n System. Inorg. Chem. 1998, 37 (21), 5467-5473. Article

Hennessy, M.H.; Wu, Y.; Bocarsly, A.B.; Soos, Z.

Electron Transfer in Symmetric Complexes: Displaced Oscillators and [Fe(CN)6Pt(NH3)4Fe(CN)6]4- Spectra. J. Phys. Chem. A. 1998, 102 (43), 8312-8319. Article

Sharp, S.L.; Kumar, G.; Vicenzi, E.P.; Bocarsly, A.B.; Heibel, M.

Formation and Structure of a Tin-Iron Oxide Solid-State System with Potential Applications in Carbon Monoxide Sensing through the Use of Cyanogel Chemistry. Chem. Mater. 1998, 10 (3), 880-885. Article

Sharp, S.L.; Bocarsly, A.B.; Scherer, G.W.

Bulk Properties of a Cyanogel Network: Toward an Understanding of the Elastic, Mechanical, and Physical Processes Associated with Sol-Gel Processing of Cyanide Bridged Gel Systems. Chem. Mater. 1998, 10 (3), 825-832. Article

VanderKam, S.K.; Bocarsly, A.B.; Schwartz, J.

Enhanced Adhesion of Poly(Ethylene-Co-Acrylic Acid) to Oxides Through Surface-Bound Alkoxyzirconium Complex Interfaces. Chem. Mater. 1998, 10 (3), 685-687. Article

Coon, D.R.; Amos, L.J.; Bocarsly, A.B.; Fitzgerald Bocarsly, P.A.

Analytical Applications of Cooperative Interactions Associated with Charge Transfer in Cyanometalate Electrodes: Analysis of Sodium and Potassium in Human Whole Blood. Anal. Chem. 1998, 70 (15), 3137-3145. Article

Kelly, M.T.; Bocarsly, A.B.

Mechanisms of Photoluminescent Quenching of Oxidized Porous Silicon: Applications to Chemical Sensing. Coord. Chem. Rev. 1998, 171, 251-259. Article

1997

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Kelly, M.T.; Bocarsly, A.B.

Effects of SO2 and I2 on the Photoluminescence of Oxidized Porous Silicon. Chem. Mater. 1997, 9 (7), 1659-1664. Article

Cheng, L.; Bocarsly, A.B.; Bernasek, S.L.; Ramanarayanan, T.A.

Adsorption and Reaction of Thiophene on the Fe(100) Surface: Selective Dehydrogenation and Polymerization. Surf. Sci. 1997, 374 (1-3), 357-372. Article

Kelly, M.T.; Chun, J.K.M.; Bocarsly, A.B.

The General Brønsted Acid Behavior of Porous Silicon: A Mechanistic Evaluation of Proton Gated Quenching of Photoemission from Oxide Coated Porous Silicon. J. Phys. Chem. B. 1997, 101 (14), 2702-2708. Article

Bocarsly, A.B.; Chang, C.C.; Wu, Y.; Vicenzi, E.P.

Inorganic Photolithography: Interfacial, Multicomponent Pattern Generation. J. Chem. Educ. 1997, 74 (6), 663-667. Article

Wu, Y.; Pfennig, B.W.; Sharp, S.L.; Ludwig, D.R.; Warren, C.J.; Vicenzi, E.P.; Bocarsly, A.B.

Light Induced Multielectron Charge Transfer Processes Occurring in a Series of Group 8-Platinum Cyanobridged Complexes. Coord. Chem. Rev. 1997, 159, 245-255. Article

Kelly, M.T.; Chun, J.K.M.; Bocarsly, A.B.

A Silicon Sensor for SO2. Nature. 1996, 382, 214-215. Article

1996

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Byrd, H.; Suponeva, E.P.; Bocarsly, A.B.; Thompson, M.E.

Photocurrent Generation in Metal Bisphosphonate Multilayer Thin Films. Nature 1996, 380, 610-612. Article

Heibel, M.; Kumar, G.; Wyse, C.; Bukovec, P.; Bocarsly, A.B.

Use of Sol-Gel Chemistry for the Preparation of Cyanogels as Ceramic and Alloy Precursors. Chem. Mater. 1996, 8 (7), 1504-1511. Article

Pfennig, B.W.; Wu, Y.; Kumble, R.; Spiro, T.G.; Bocarsly, A.B.

Time-Dependent Resonance Raman Analysis of a Trinuclear Mixed Valence Coordination Complex. J. Phys. Chem. 1996, 100 (14), 5745-5750. Article

Warren, C.J.; Haushalter, R.C.; Bocarsly, A.B.

Electrochemical Synthesis of a Pseudo Two-Dimensional Polytelluride Containing Te122- Anions: Structure of [(C2H5)4N]2Te12. J. Alloys Compd. 1996, 233 (1-2), 23. Article

Du, G.; Lin, C.; Bocarsly, A.B.

Electroanalytical Detection of Glucose Using a Cyanometalate Modified Electrode: Requirements for the Oxidation of Buried Redox Sites in Glucose Oxidase. Anal. Chem. 1996, 68 (5), 796-806. Article

Cheng, L.; Bocarsly, A.B.; Bernasek, S.L. (Princeton University); Ramanarayanan, T.A. (Exxon Research and Engineering Company).

Coadsorption of Ethanethiol with Sulfur, Oxygen, and Water on the Fe(100) Surface. Langmuir. 1996, 12 (2), 392-401. Article

1995

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Warren, C.J.; Haushalter, R.C.; Bocarsly, A.B.

The Electrochemical Synthesis of Telluride Zintl Anions. J. Alloys Compd. 1995, 229 (1), 175-205. Article

Wu, Y.; Pfennig, B.W.; Vicenzi, E.P.; Bocarsly, A.B.

Development of Redox-Active Optical Mesostructures at Chemically Modified Electrode Interfaces. Inorg. Chem., 1995, 34 (16), 4262-4267. Article

Cheng, L.; Bernasek, S.L.; Bocarsly, A.B.; Ramanarayanan, T.A.

Adsorption and Decomposition of 1-Alkanethiols on the Fe(100) Surface. Chem. Mater. 1995, 7 (10), 1807-1815. Article

Dhingra, S.S.; Warren, C.J.; Haushalter, R.C.; Bocarsly, A.B.

One-Dimensional Mercury Telluride Polymers: Synthesis and Structure of (Et4N)2Hg2Te4 and (Me4N)4Hg3Te7.(0.5en). Chem. Mater. 1994, 6 (12), 2382-2385. Article

1994

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Cheng, L.; Bocarsly, A.B.; Bernasek, S.L.; Ramanarayanan, T.A.

The Interaction of Alkanethiols with Single Crystal Iron: The Low Temperature Decomposition of Ethanethiol on the Fe(100) Surface. Langmuir. 1994, 10 (12), 4542-4550. Article

Wu, Y.; Cohran, C.; Bocarsly, A.B.

The Construction of Molecular Systems Capable of Photoinduced Multielectron Charge Transfer: A Photochemical Analysis of The Reactivity of [(CN)5FeII-(CN)-PtIV(L)4-FeII(CN)5]4-(L=NH3, ethylenediamine. Inorg. Chim. Acta. 1994, 226 (1-2), 251-258. Article

Warren, C.J.; Haushalter, R.C.; Bocarsly, A.B.

Electrochemical Synthesis and Structural Characterization of the One Dimensional Chain Compound (Et4N)2[As2Te5] and the Tellurido Arsenate (Me4N)4[As4Te6].2en. Chem. Mater. 1994, 6 (6), 780-783. Article

Kelly, M.T.; Chun, J.K.M.; Bocarsly, A.B.

High Efficiency Chemical Etchant for the Formation of Luminescent Porous Silicon. Appl. Phys. Lett. 1994, 64, 1693-1695. Article

1993

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Bocarsly, A.B.; Chun, J.K.M.; Kelly, M.T.

Selective Detection of SO2(g) at the P-Type Porous Silicon Gas Interface: Photophysical Evaluation of Interfacial Chemistry. In Chemically Sensitive Interfaces; Mallouk, T., Harrison, D.J., Eds.; ACS Symposium Series 561; American Chemical Society: 1993; pp 78-90. Article

Warren, C.J.; Dhingra, S.S.; Ho, D.M.; Haushalter, R.C.; Bocarsly, A.B.

Electrochemical Synthesis of Sb-Te Zintl Anions by Cathodic Dissolution of Sb2Te3 Electrodes: Structures of Sb2Te54- and Sb6Te94-. Inorg. Chem. 1994, 33 (13), 2709-2710. Article

Warren, C.J.; Dhingra, S.S.; Haushalter, R.C.; Bocarsly, A.B.

Electrochemical Synthesis of a New Indium Telluride Containing One-Dimensional Chains: Structure of [(n-C4H9)4N]2In2Te4. J. Solid State Chem. 1994, 112 (2), 340-344. Article

Warren, C.J.; Ho, D.M.; Haushalter, R.C.; Bocarsly, A.B.

Electrochemical Synthesis of a New Gallium Telluride Containing One-Dimensional Chains: Structure of [(C6H5)4P]GaTe2(en)2 (en = ethane-1,2-diamine). J. Chem. Soc., Chem. Commun. 1994 (3), 361-363. Article

Seshadri, G.; Chao, L.; Bocarsly, A.B.

A New Homogeneous Electrocatalyst for the Reduction of Carbon Dioxide to Methanol at Low Overpotential. J. Electroanal. Chem. 1994, 372 (1-2), 145-150. Article

Warren, C.J.; Ho, D.M.; Haushalter, R.C.; Bocarsly, A.B.

Electrochemical Synthesis of New Sb-Te Zintl Anions by Cathodic Dissolution of Sb2Te3 Electrodes: Structures of Sb4Te44- and Sb9Te63-. Angew. Chem. Int. Ed. 1993, 32 (11), 1646-1648. Article

Warren, C.J.; Ho, D.M.; Bocarsly, A.B.; Haushalter, R.C.

Electrochemical Synthesis of New Au-Te Polyanion by the Cathodic Dissolution of a Gold Telluride (AuTe2) Electrode: Structure of Telluroaurate (Au3Te43-). J. Am. Chem. Soc., 1993, 115 (14), 6416-6417. Article

Pfennig, B.W.; Thompson, M.E.; Bocarsly, A.B.

Luminescent d0 Scandocene Complexes: Photophysical Studies and Electronic Structure Calculations on Cp*2ScX, X=Cl, I, Me. Organometallics, 1993, 12 (3), 649-655. Article

Chun, J.K.M.; Bocarsly, A.B.; Cottrell, T.R.; Benziger, J.B.; Yee, J.C.

Proton Gated Emission from Porous Silicon. J. Am. Chem. Soc., 1993, 115 (7), 3024-3025. Article

Pfennig, B.W.; Bocarsly, A.B.; Prud’homme, R.K.

Synthesis of a Novel Hydrogel Based on a Coordinate Covalent Polymer Network. J. Am. Chem Soc., 1993, 115 (7), 2661-2665. Article

1992

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Bocarsly, A.B.

Comment on: “Rational Electrolyte Modifications of n-CdSe/([KFE(CN)6]3–/2–) Photoelectrochemistry” [J. Electrochem. Soc., 139, L23]. J. Electrochem. Soc. 1992, 139 (6), 1791-1792. Article

Bocarsly, A.B.

Photoelectrochemistry: Converting Light to Electricity and Chemicals. Chem. Ind. 1992, 21, 813 (invited paper). Article

Pfennig, B.W.; Bocarsly, A.B.

The Design of Reagents for Photochemical and Thermal Multiple Electron Transfer Reactions. Comments Inorg. Chem. 1992, 13 (5), 261-275 (invited paper). Article

Luangdilok, C.H.; Arent, D.J.; Wood, R.; Bocarsly, A.B.

Investigation of the Structure Reactivity Relationship in the Pt/MxCdFe(CN)6 Modified Electrode System. Langmuir. 1992, 8 (2), 650-657. Article

Pfennig, B.W.; Bocarsly, A.B.

Optical and Thermal Charge Transfer Processes Occurring in a Series of Three-Centered Cyanide Bridged Intervalent Charge Transfer Complexes. J. Phys. Chem. 1992, 96 (1), 226-233. Article

Arent, D.J.; Rubin, H.D.; Bocarsly, A.B.

Cadmium Ferrocyanide Overlayers: Regulation of Photoinduced Charge Transfer at the n-CdSe/Fe(CN)64-/3- Interface. J. Electrochem. Soc. 1992, 139 (10), 2705-2712. Article

Arent, D.J.; Luangdilok, C.H.; Chun, J.K.M.; Bocarsly, A.B.

The Roles of Cesium Ions in Regulating Photoinduced Interfacial Charge Transfer at the n-Type Cadmium Chalcogenide/Ferrocyanide Interface. J. Electroanal. Chem. 1992, 328 (1-2), 295-310. Article

1991

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Pfennig, B.W.; Bocarsly, A.B.

Photoinduced Multielectron Charge Transfer in the Polymetallic Intervalent Complex [(NC)5Fe-CN-Pt(NH3)4-Ne-Fe(CN)5]4- and Related Species. Coord. Chem. Rev. 1991, 111, 91-96. Article

Seshadri, G.; Chun, J.K.M.; Bocarsly, A.B.

The Effect of Dissolved Cyanide on the Photoelectrochemical Response of n-CdSe/Fe(CN)64-/3- Electrolytic Cells. Nature 1991, 352, 508-510. Article

Pfennig, B.W.; Bocarsly, A.B.

Surface Attached [(NC)5Fe-CN-Pt(NH3)4-NC-Fe(CN)5]4-: A Study in the Electrochemical and Photochemical Control of Surface Morphology. Inorg. Chem. 1991, 30 (4), 666-672. Article

Lin, C.; Bocarsly, A.B.

Catalytic Electrooxidation of Hydrazine at the Nickel Ferricyanide Modified Electrode: Can an Array of Surface Bound One Electron Redox Centers Act in Concert? J. Electroanal. Chem. 1991, 300 (1-2), 325-345. Article

Zhou, M.; Pfennig, B.W.; Steiger, J.; Van Engen, D.; Bocarsly, A.B.

Multielectron Transfer and Single Crystal X-ray Structure of a Trinuclear Cyanide-Bridged Platinum-Iron Species. Inorg. Chem. 1990, 29 (13), 2456-2460. Article

Hidalgo-Luangdilok, C.; Bocarsly, A.B.

Nickel Electrode Confined [Ru(Bipyrazine)3{Fe(CN)5}n]2-3n: An Inorganic Structural Matrix Yielding Photoinduced Multinuclear Charge Transfer Reactivity. Inorg. Chem. 1990, 29, (16) 2894-2900. Article

Hidalgo-Luangdilok, C.; Bocarsly, A.B.; Woods, R.E.

Electrochemically Modulated Photoluminescence at the Chemically Derivatized Electrode: [CdRu(CN)4(bpy)]0/+ Modified Electrodes. J. Phys. Chem., 1990, 94 (5), 1918-1924. Article

Pfennig, B.W.; Bocarsly, A.B.

A New Class of Room Temperature Luminescent Organometallic Complexes: Luminescence and Photophysical Properties of Permethyl Scandocene Chloride in Fluid Solution. J. Am. Chem. Soc. 1989, 111 (24), 8947-8948. Article

Arbuckle, G.A.; Chen, Y.; Hidalgo-Luangdilok, C.; Bocarsly, A.B.

Electrochemical Reactivity of Ultra-Thin Cyanometallate Films on Electrode Surfaces. Solid State Ionics. 1988, 32-33, 941-945. Article

Norton, A.P.; Bernasek, S.L.; Bocarsly, A.B.

Mechanistic Aspects of the Photooxidation of Water at the n-TiO2/Aqueous Interface: Optically Induced Transients as a Kinetic. J. Phys. Chem. 1988, 92 (21), 6009-6016. Article

Bocarsly, A.B.; Amos, L.J.; Duggal, A.; Mirsky, E.; Ragonesi, P.; Fitzgerald-Bocarsly, P.A.

Morphological Variation at the [NiFe(CN)6]2- /1- Derivatized Nickel Electrode: A Technique for the Evaluation of Alkali Cation Containing Solutions. Anal. Chem. 1988, 60 (3), 245-249. Article

Rubin, H.D.; Arent, D.J.; Humphrey, B.D.; Bocarsly, A.B.

Overlayer Formation as a Source of Stability in the n-Type Photoelectrochemical Cell: The n-CdS/Fe(CN)64- /3- Cell. J. Electrochem. Soc. 1987, 134 (1), 93-101. Article

Humphrey, B.D.; Sinha, S.; Bocarsly, A.B.

Mechanisms of Charge Transfer at the Chemically Derivatized Interface: The Ni/[NiII(CN)FeII/III(CN)5]2-/1- System as an Electrocatalyst. J. Phys. Chem., 1987, 91 (3), 586-593. Article

Amos, L.J.; Schmidt, M.H.; Sinha, S.; Bocarsly, A.B.

Overlayer-Support Interactions Associated with the Formation of a Chemically Modified Interface: The Nickel Ferrocyanide Derivatized Nickel Electrode. Langmuir 1986, 2 (5), 559-561. Article

Cameron, R.E.; Bocarsly, A.B.

Multielectron Photoinduced Reduction of Chloroplatinum Complexes: Visible Light Deposition of Platinum Metal. Inorg. Chem. 1986, 25 (16), 2910-2913. Article

Sinha, S.; Amos, L.J.; Schmidt, M.H.; Bocarsly, A.B.

Metallocyanide Modified Nickel Electrode Surfaces: Enhanced Currents From Solution Species. J. Electroanal. Chem. 1986, 210 (2), 323-328. Article

Cameron, R.E.; Bocarsly, A.B.

Photoactivated Oxidation of Alcohols by Oxygen. J. Am. Chem. Soc., 1985, 107 (21), 6116-6117. Article

Bocarsly, A.B.; Cameron, R.E.; Rubin, H.D.; McDermott, G.A.; Mayr, A.

Photoemission from Tungsten Alkylidyne Complexes in Fluid Solution. Inorg. Chem. 1985, 24 (24), 3976-3978. Article

Crerar, D.; Wood, S.; Brantley, S.; Bocarsly, A.B.

Chemical Controls on Solubility of Ore-Forming Minerals in Hydrothermal Solutions. Canadian Mineralogist, 1985, 23 (3), 333-352. Article

Rubin, H.D.; Arent, D.J.; Bocarsly, A.B.

A Novel Wavelength Dependence Associated with the n-CdSe Based Photoelectrochemical Cell: The Role of Ferrocyanide as a Stabilizing Electrolyte. J. Electrochem. Soc. 1985, 132 (2), 523-524. Article

Hamilton, A.D.; Rubin, H.D.; Bocarsly, A.B.

Binuclear Complexes of a Novel Covalently-Linked Porphyrin-Bipyridine Ligand. J. Am. Chem. Soc. 1984, 106 (23), 7255-7257. Article

Sinha, S.; Humphrey, B.D.; Fu, E.; Bocarsly, A.B.

The Coordination Chemistry of Chemically Derivatized Nickel Surfaces: Generation of an Electrochromic Interface. J. Electroanal. Chem. 1984, 162 (1-2), 351-357. Article

Rubin, H.D.; Humphrey, B.D.; Bocarsly, A.B.

The Role of Surface Reactions in the Stabilization of n-CdS Based Photoelectrochemical Cells. Nature. 1984, 308, 339-341. Article

Humphrey, B.D.; Sinha, S.; Bocarsly, A.B.

Diffuse Reflectance Spectroelectrochemistry as a Probe of the Chemically Derivatized Electrode Interface: The Derivatized Nickel Electrode. J. Phys. Chem. 1984, 88 (4), 736-743. Article

Sinha, S.; Humphrey, B.D.; Bocarsly, A.B.

The Reaction of Nickel Electrode Surfaces with Metal-Cyanide Anionic Complexes: The Formation of Precipitated Surfaces. Inorg. Chem. 1984, 23 (2), 203-212. Article

Gladysz, J.A.; Fulcher, J.G.; Bocarsly, A.B.

Atomos De Metales De Transicion En La Sintesis Y La Catalisis Organica. Rev. Soc. Quim. Mex. 1983, 27, 146. Article

Royce, B.S.H.; Voss, D.; Bocarsly, A.B.

Mirage Effect Studies of Electrochemical Process. J. Phys. Colloques 1983, 44, C6-325-C6-329. Article

Bocarsly, A.B.; Galvin, S.A.; Sinha, S.

Properties of Chemically Derivatized Nickel Electrodes: The Synthesis of an Electrocatalytic Interface. J. Electrochem. Soc. 1983, 130 (6), 1319-1325. Article

Bocarsly, A.B.; Sinha, S.

Effects of Surface Structure on Electrode Charge Transfer Properties: Induction of Ion Selectivity at the Chemically Derivatized Interface. J. Electroanal. Chem. 1982, 140 (1), 167-172. Article

Bocarsly, A.B.; Sinha, S.

Chemically Derivatized Nickel Surfaces: Synthesis of a New Class of Stable Electrode Interfaces. J. Electroanal. Chem. 1982, 137 (1), 157-162. Article

Lewis, N.S.; Bocarsly, A.B.; Wrighton, M.S.

Heterogenous Electron Transfer at Designed Semiconductor/Liquid Interfaces: Rate of Reduction of Surface-Confined Ferricenium Centers by Solution Reagents. J. Phys. Chem. 1980, 84 (16), 2033-2043. Article

Bocarsly, A.B.; Bookbinder, D.C.; Dominey, R.N.; Lewis, N.S.; Wrighton, M.S.

Photoreduction at Illuminated p-Type Semiconducting Silicon Photo-Electrodes: Evidence for Fermi Level Pinning. J. Am. Chem. Soc. 1980, 102 (11), 3683-3688. Article

Bard, A.J.; Bocarsly, A.B.; Fan, F.F.; Walton, E.G.; Wrighton, M.S.

Concept of Fermi Level Pinning at Semiconductor/Liquid Junctions: Consequences for Energy Conversion Efficiency and Selection of Useful Solution Redox Couples in Solar Devices. J. Am. Chem. Soc. 1980, 102 (11), 3671-3677. Article

Bocarsly, A.B.; Walton, E.G.; Wrighton, M.S.

Use of Chemically Derivatized n-Type Silicon Photoelectrodes in Aqueous Media: Photo-oxidation of Iodide, Hexacyanoiron (II), and Hexammineruthenium (II) at Ferrocene-Derivatized Photoanodes. J. Am. Chem. Soc. 1980, 102 (10), 3390-3398. Article

Lee Hanlan, A.J.; Ugolick, R.C.; Fulcher, J.G.; Togashi, S.; Bocarsly, A.B.; Gladysz, J.A.

Chemistry via Metal Atom Cocondensation: Isomerization and Complexation Reactions of Organocyclopropanes and Spirocycles. Inorg. Chem. 1980, 19 (6), 1543-1551. Article

Bookbinder, D.C.; Lewis, N.S.; Bradley, M.G.; Bocarsly, A.B.; Wrighton, M.S.

Photoelectrochemical Reduction of N, N’-Dimethyl-4,4′-Bipyridinium in Aqueous Media at P-Type Silicon: Sustained Photogeneration of a Species Capable of Evolving Hydrogen. J. Am. Chem. Soc. 1979, 101 (26), 7721-7723.

Article

Wrighton, M.S.; Bocarsly, A.B.; Bolts, Bradley, M.G.; Fishcer, A.B.; Lewis, N.S.; Palazzotto, M.C.; Walton, E.G.

Chemically Derivatized Semiconductor Photoelectrodes: A Technique for the Stabilization of n-Type Semiconductors. Adv. Chem. Ser. 1979, 184, 269-294. Article

Bocarsly, A.B.; Walton, E.G.; Bradley, M.G.; Wrighton, M.S.

Two-Electron Oxidations at Illuminated n-Type Semiconducting Silicon Electrodes: Use of Chemically Derivatized Photoelectrodes. J. Electroanal. Chem. 1979, 100 (1-2), 283-306. Article

Gladysz, J.A.; Fulcher, J.G.; Ugolick, R.C.; Lee Hanlan, A.J.; Bocarsly, A.B.

Reactions of Organocyclopropanes and Spirocycles with Metal Atoms. J. Am. Chem. Soc. 1979, 101 (12), 3388-3390. Article

Bolts, J.M.; Bocarsly, A.B.; Palazzotto, M.C.; Walton, E.G.; Lewis, N.S.; Wrighton, M.S.

Chemically Derivatized n-Type Silicon Photoelectrodes: Stabilization to Surface Corrosion in Aqueous Electrolyte Solutions and Mediation of Oxidation Reactions by Surface-Attached Electroactive Ferrocene Reagents. J. Am. Chem. Soc. 1979, 101 (6), 1378-1385. Article

Wrighton, M.S.; Palazzotto, M.C.; Bocarsly, A.B.; Bolts, J.M.; Fischer, A.B.; Nadjo, L.

Preparation of Chemically Derivatized Platinum and Gold Electrode Surfaces: Synthesis, Characterization, and Surface Attachment of Trichlorosilylferrocene, (1,1′-ferrocenediyl) dichlorosilane, and 1,1′-Bis(triethoxysilyl) ferrocene. J. Am. Chem. Soc. 1978, 100 (23), 7264-7271. Article

Wrighton, M.S.; Bolts, J.M.; Bocarsly, A.B.; Palazzotto, M.C.; Walton, E.G.

Stabilization of n-Type Semiconductors to Photoanodic Dissolution: II-VI and III-V Compound Semiconductors and Recent Results for n-Type Silicon. J. Vac. Sci. Technol. 1978, 15 (4), 1429-1435. Article

Wrighton, M.S.; Austin, R.G.; Bocarsly, A.B.; Bolts, J.M.; Haas, O.; Legg, K.D.; Nadjo, L.; Palazzotto, M.C.

A Chemically Derivatized Platinum Electrode: Persistent Attachment of an Inert Electroactive Ferrocene Derivative. J. Electroanal. Chem. 1978, 87 (3), 429-433. Article

Wrighton, M.S.; Austin, R.G.; Bocarsly, A.B.;

Design and Study of a Photosensitive Interface: Chemically Derivatized Silicon Photoelectrodes. J. Am. Chem. Soc. 1978, 100 (5), 1602-1603. Article

Gladysz, J.A.; Fulcher, J.G.; Bocarsly, A.B.

Ligand Wrapping Around Chromium: Reactions of Diphenylmethane, 1,4-Diphenylbutane, Benzyl Ether, and Benzyl Sulfide with Chromium Atoms. Tetrahedron Lett., 1978, <i?19 (20), 1725-1728. Article

Bocarsly, A.B.; Bolts, J.M.; Cummins, P.G.; Wrighton, M.S.

Photoelectrolysis of Water at High Current Density: Use of UltraViolet Laser Excitation. Appl. Phys. Lett., 1977, 31 (9), 568-560. Article

Gladysz, J.A.; Fulcher, J.G.; Lee, S.J.; Bocarsly, A.B.

Cyclotrimerization of Cyclic Diynes via Metal Atom Cocondensation: Revised Structure for the Reported ‘Percyclophone – 4’. Tetrahedron Lett. 1977, 18 (39), 3421. Article

Book Chapters

Paris, A. R.; Frick, J. J.; Ni, D.; Smith, M. R.; Bocarsly, A. B.

Electrochemical and Photoelectrochemical Transformations of Aqueous CO2. In An Economy Based on Carbon Dioxide and Water, M. Aresta et al., Editors. 2019, Springer: Switzerland. p. 239-286. Article

Yan, Y.; Gu, J.; Zeitler, E. L.; Bocarsly, A. B.

Photoelectrocatalytic Reduction of Carbon Dioxide. In Carbon Dioxide Utilisation: Closing the Carbon Cycle, P. Styring et al., Editors. 2014, Elsevier: Amsterdam. p. 211-231. Article

Barton-Cole, E.; Bocarsly, A.B.

Photochemical, Electrochemical, and Photoelectrochemical Reduction of Carbon Dioxide. In Carbon Dioxide as Chemical Feedstock, M. Aresta, Editor. 2010, Wiley-VCH Verlag GmbH & Co.: Weinheim. Article

Bocarsly, A.B.; Niangar, E.V.

Elevated Temperature Membranes. In Encyclopedia of Electrochemical Power Sources, J. Garche, et al., Editors. 2009, Elsevier: Amsterdam. p. 724-733. Article

Bocarsly, A.B.; Cole, E.B.

Conversion of Carbon Dioxide to Alcohols. U.P.O. Pending, Editor. 2009, Princeton University: United States. Article

Zhu, S.; Bocarsly, S.

Spin-coated Cyanogels. In Dekker Encyclopedia of Nanoscience and Nanotechnology. Schwartz, J.A.; Contescu, C.I.; Putyera, K., Eds.; 3667-3674, 2004. Article

Watson, D.F.; Bocarsly, A.B.; Schreiber, E.

Pump-Probe Spectroscopy of a Trinuclear Transition Metal Mixed-Valence Complex: Solvent Dependence of Back Electron Transfer Rate. Nanostructures, Polymers, Surfaces and Interfaces. In Femtochemistry and Femtobiology: Ultrafast Dynamics in Molecular Science; Douhal, A., Santamaria, J.. Eds.; World Scientific, 2002; pp 664-673. Article

Bocarsly, A.B.

Unexpected Contributions from Partners in Science. In Bringing the Excitement of Science to the Classroom; Bacon, W.S., Ed.; Research Corporation: Tucson, Arizona, 2000; pp 15-20. Article

Su, E.Y.; Bocarsly, A.B.

Electroanalytical Chemistry in Clinical Analysis. In Encyclopedia of Analytical Chemistry; Meyers, R.A., Ed.; John Wiley & Sons Limited, 2000. Article

Bocarsly, A.B.

Cyclic Voltammetry. In Methods in Materials Research; Current Protocols, Division of John Wiley & Sons Limited, 2000. Article

Mathauser, A.; Kelly, M.T.; Mayo, W.E.; Bocarsly, A.B.; Arbuckle, G.A.

In Situ X-ray Powder Diffraction Study of Electrochemically induced Structural Changes on Nickel Electrodes Modified with Ferricyanide. Presented at the Eastern Analytical Symposium, November 1997. Article

Bernasek, S.L.; Shafer, K.E.; Cheng, L.; Meager, K.K.; Bocarsly, A.B.

Surface Oligomerization of Sulfur-Containing Molecules on Fe(100). In ECOSS-17 Proceedings, 1997. Article

Heibel, M.; Bocarsly, A.B.

Sol-Gel Processing of Inorganic Cyanogels. In ISMANAM-95, Proceedings of the International Symposium on Metastable, Mechanically Alloyed and Nanocrystalline Materials, Quebec, Canada, 1995. Article

Bocarsly, A.B.; Tachikawa, H.; Faulkner, L.R.

Photonic Electrochemistry. In Laboratory Techniques in Electroanalytical Chemistry, 2nd ed.; Kissinger, P.T., Heineman, W.R., Eds.; Marcel Dekker: New York, 1996; Chapter 28 Article

Wu, Y.; Pfennig, B.W.; Bocarsly, A.B. (Princeton University); Vicenzi, E.P. (Princeton Materials Institute).

Synthesis of Redox Active Optical Mesostructures at the Cyanometalate Modified Electrode Interface. Proceedings of Microstructures and Microfabricated Systems II; Denton, D.; Hesketh, P.J.; Hughes, H., Eds.; Electrochemical Society, Inc.: 1995, Vol. 95-27, 167-176. Article

Panitz, E.B.; Rieders, F.; Bocarsly, A.B.

Environmental Arsenic and Selenium Poisoning. In Hazardous Waste and Public Health: International Congress on the Health Effects of Hazardous Waste, Proceedings of the U. S. Department of Health and Human Services; Andrews, J.S., Jr.; Frumkin, H.; Johnson, B.L.; Mehlman, M.A.; Xintaras, C.; Bucsela, J.A., Eds.; Princeton Scientific Publishing Co.: 1994; 834-849. Article

Bocarsly, A.B.; Kumar, G.; Heibel, M.

Novel Inorganic Hydrogels Based on the Polymerization of Cyanometalate Transition Metal Complexes with [PdCl4]2-: A New Approach to Ceramic and Alloy Precursors. Proceedings of the Spring Materials Research Society Meeting, 1994; Vol. 346, 89-94. Article

Bocarsly, A.B.; Seshadri, G.; Chao, L.;

The Efficient Reduction of CO2 to Methanol at Platinum and Palladium Electrodes Using a Pyridinium Catalyst. In Environmental Aspects of Electrochemistry and Photoelectrochemistry, Proceedings of the Electrochemical Society; Yoneyama, H., Hori, Y., Haynes, R., Tomkiewicz, T., Eds.; The Electrochemical Society: Honolulu, Hawaii, 1993, pp. 30-37. Article

Du, G.; Lin, C.; Bocarsly, A.B.

Electroanalytical Detection of Glucose Using A Cyanometallate Modified Electrode: Requirements for Oxidation of Buried Redox Sites in Glucose Oxidase. Proceedings of the Fifth International Symposium on Redox Mechanisms and Interfacial Properties of Molecules of Biological Importance. Schultz, F.A., Taniguchi, I., Eds.; The Electrochemical Society, Inc.: Pennington, New Jersey, 1993, Vol. 93-11 Article

Chun, J.K.M.; Bocarsly, A.B.

Porous Si as a Novel Photoluminescent Sensor for SO2 Detection. In Chemical Sensors II, Proceedings of the Electrochemical Society; Ricco, A., Butler, M., Yamazue, N., Eds.; The Electrochemical Society: Honolulu, Hawaii, 1993, Vol. 93-7, pp. 650-655. Article

Chun, J.K.M.; Bocarsly, A.B.; Cottrell, T.R.; Benziger, J.B.; Yee, Y.C.

Brønsted and Lewis Base Quenching of Photoemission from Luminescent ‘Porous Silicon’: In Surface Protons in the Luminescence Mechanism. Microcrystalline Semiconductors-Materials Science & Devices, Proceedings of the Materials Research Society Symposium; Aoyagi, Y., Canhan, L.T., Fauchet, P.M., Shimizu, I., Tsai, C.C., Eds.; Boston, Massachusetts, 1993; Vol. 283, pp. 329-333. Article

Cottrell, T.R.; Benziger, J.B.; Yee, J.C.; Chun, J.K.M.; Bocarsly, A.B.

Organic-Inorganic Junctions formed on Porous Silicon: Isolation of a Surface Configuration primary to the Luminescence Mechanism. In Microcrystalline Semiconductors-Materials Science & Devices, Proceedings of the Materials Research Society Symposium; Aoyagi, Y.; Canhan, L.T.; Fauchet, P.M.; Shimizu, I.; Tsai, C.C., Eds.; Boston, Massachusetts, 1993, Vol. 283, pp. 411-416. Article

Seshadri, G.; Chun, J.K.M.; Bocarsly, A.B.

Interfacial Chemistry as a Controlling Element in Photoinduced Charge Transfer in n-Type Cadmium Chalconide/Fe(CN)64-/3- Cells. In Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XI: Photovoltaics, Photochemistry, and Photoelectrochemistry; Hugot-Le Goff, A., Granqvist, C.-G., Lampert, C.M., Eds.; Proc. SPIE: 1992, Vol. 1729, pp. 61-71. Article

Zhou, M.; Cameron, R.E.; Schwab, F.J.; Bocarsly, A.B.

Photolithographic Plating of Platinum and Copper on Insulating Substrates. In Metallized Plastics 2: Fundamental and Applied Aspects; Mittal, K.L., Ed.; 1991; pp. 57-71. Article

Gonsalves, K.; Parekh, P.; Holland, R.; Bocarsly, A.B.; Arbuckle, G.

An Investigation of a Chemically Derivatized Copper-Polyimide Interface. In Polyimides: Materials, Chemistry and Characterization, Proceedings of the Third International Conference on Polyimides, Ellenville, New York, 1988; Feger, C., Khojasteh, M.M., McGrath, J.E., Eds.; Elsevier: 1989; 695-703. Article

Parekh, P.P.; Kembaiyan, K.T.; Gonsalves, K.; Bocarsly, A.B.; Amos, L.J.

Modification of Copper Surfaces: Effects on Adhesion at the Copper-Polyimide Interface. In Adhesions in Solids, Proceedings of the Materials Research Society Symposium; Mattox, D.M., Ed.; Materials Research Society: 1988; Vol. 119. Article

Lewis, N.S.; Bocarsly, A.B.

Silicon and Germanium. In Semiconductor Electrodes; Finklea, H.O., Ed.; Elsevier Science Publishers: 1988; Ch. 5, 241-276. Article

Bocarsly, A.B.; Cameron, R.E.; Mayr, A.; McDermont, G.A.

Photophysics and Photochemistry of Tungsten Carbyne Complexes. Proceedings of the Seventh International Symposium on the Photochemistry and Photophysics of Coordination Compounds; Vogler, A., Yersin, H., Eds. Springer-Verlag 1987, 213-216. Article

Bocarsly, A.B.; Cameron, R.E.; Zhou, M.

Photoinduced Multielectron Redox Reactions in the [PtCl6]2-/Alcohol System: Visible Light Reduction of Platinum Centers, Proceedings of the Seventh International Symposium on the Photochemistry and Photophysics of Coordination Compounds; Vogler, A., Yersin, H., Eds.; Springer-Verlag: 1987, pp. 177-180. Article

Bocarsly, A.B.; Galvin, S.A.; Sinha, S.

Properties of Chemically Derivatized Nickel Electrodes. In The Nickel Electrode, Proceedings of the Electrochemical Society, 1982; Gunther, R.G., Gross, S., Eds.; Volume 82-4, pp. 97-117. Article

Wrighton, M.S.; Bocarsly, A.B.; Bolts, J.M.

Photoelectrolysis of Water at High Current Density: Use of Laser Light Excitation of Semiconductor-Based Photoelectrochemical Cells. In Radiation Energy Conversion in Space, K. W. Billman, Ed., Vol. 61, Progress in Astronautics and Aeronautics, 1978, p. 613-625. Article

Wrighton, M.S.; Bocarsly, A.B.; Bolts, J.M.; Ellis, A.B.; Legg, K.D.

Stabilization of n-Type Semiconductors to Photoanodic Dissolution by Competitive Electron Transfer Processes. In Semiconductor Liquid-Junction Solar Cells, Proceedings of the Electrochemical Society, Heller, A., Ed.; The Electrochemical Society: 1977; 77-3, pp. 138-156. Article

Patents

Bocarsly, A.; Paris, A.; Francis, S.A.; Chu, A.

Binary Alloys and Oxides Thereof for Electrocatalytic Reduction of Carbon Dioxide. International Application No.: PCT/US2018/050016, Patent Application submitted 2018.

Bocarsly, A.B.; Srinivasan, S.; Lee, S.J.; Adjemian, K.

High Temperature, Carbon Monoxide-Tolerant Perfluorosulfonic Acid Composite Membranes and Methods of Making Same. Invention #01-1789-1, Patent Application submitted 2002. Article

Bocarsly, A.B.; Wimbish, J.C.

Surface Modification of Porous Silicon. Invention #00-1792-1, Patent Application submitted 2002. Article

Bocarsly, A.B.; Zhu, S.

Novel Methodology for the Synthesis of Near Monodispersed Metallic Alloy Particles Having Nanometer Dimensions. Invention #02-1875-1, Patent Application submitted 2002. Article

Warren, C.J.; Haushalter, R.C.; Bocarsly, A.B.

Process for Forming Zintl Phases and the Products Thereof. U.S. Patent 5,368,701, 1994. Article